Two azolium rings are better than one: A strategy for controlling catenation and morphology in Zn and Cu metal - Organic frameworks

John M. Roberts; Omar K. Farha; Amy A. Sarjeant; Joseph T. Hupp; Karl A. Scheidt

doi:10.1021/cg2011309

Two azolium rings are better than one: A strategy for controlling catenation and morphology in Zn and Cu metal - Organic frameworks

John M. Roberts, Omar K. Farha, Amy A. Sarjeant, Joseph T. Hupp, Karl A. Scheidt^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

49 Scopus citations

Abstract

Four new azolium-containing metal - organic frameworks (MOFs) have been synthesized, where the azoliums are potential organocatalyst precursors. Modifying the number of azoliums on a standard biphenyl dicarboxylate strut affects the morphology or the degree of interpenetration in two representative types of MOFs: NbO-type Cu-paddlewheel 2D sheets and cubic IRMOFs.

Original language	English (US)
Pages (from-to)	4747-4750
Number of pages	4
Journal	Crystal Growth and Design
Volume	11
Issue number	11
DOIs	https://doi.org/10.1021/cg2011309
State	Published - Nov 2 2011

ASJC Scopus subject areas

General Chemistry
General Materials Science
Condensed Matter Physics

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10.1021/cg2011309

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abstract = "Four new azolium-containing metal - organic frameworks (MOFs) have been synthesized, where the azoliums are potential organocatalyst precursors. Modifying the number of azoliums on a standard biphenyl dicarboxylate strut affects the morphology or the degree of interpenetration in two representative types of MOFs: NbO-type Cu-paddlewheel 2D sheets and cubic IRMOFs.",

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AU - Scheidt, Karl A.

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N2 - Four new azolium-containing metal - organic frameworks (MOFs) have been synthesized, where the azoliums are potential organocatalyst precursors. Modifying the number of azoliums on a standard biphenyl dicarboxylate strut affects the morphology or the degree of interpenetration in two representative types of MOFs: NbO-type Cu-paddlewheel 2D sheets and cubic IRMOFs.

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Two azolium rings are better than one: A strategy for controlling catenation and morphology in Zn and Cu metal - Organic frameworks

Abstract

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CCDC 827081: Experimental Crystal Structure Determination

CCDC 827080: Experimental Crystal Structure Determination

CCDC 827082: Experimental Crystal Structure Determination

Cite this

Two azolium rings are better than one: A strategy for controlling catenation and morphology in Zn and Cu metal - Organic frameworks

Abstract

ASJC Scopus subject areas

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Datasets

CCDC 827081: Experimental Crystal Structure Determination

CCDC 827080: Experimental Crystal Structure Determination

CCDC 827082: Experimental Crystal Structure Determination

Cite this