Two large-pore metal-organic frameworks derived from a single polytopic strut

Ibrahim Eryazici; Omar K. Farha; Brad G. Hauser; A. Özgür Yazaydin; Amy A. Sarjeant; Sonbinh T. Nguyen; Joseph T. Hupp

doi:10.1021/cg201520z

Two large-pore metal-organic frameworks derived from a single polytopic strut

Ibrahim Eryazici, Omar K. Farha^*, Brad G. Hauser, A. Özgür Yazaydin, Amy A. Sarjeant, Sonbinh T. Nguyen, Joseph T. Hupp

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

30 Scopus citations

Abstract

Two noninterpenetrated MOFs with strikingly different structures, NU-108-Cu and NU-108-Zn, were prepared from a single hexa-carboxylated ligand. NU-108-Cu contains paddlewheel-coordinated copper ions as nodes and is based on a 3,24 network associated with an inherently noncatenating rht-topology. Modifications introduced in the hexa-carboxylated struts (uniquely placed phenyl spacers) lead to substantial changes in pore sizes, relative to those found in other MOFs based on 3,24 networks and paddlewheel-coordinated copper ions. NU-108-Zn features a new net based on (3,3,6)-connecter and octadehral Zn ₄O nodes in which all struts lie in a-b planes.

Original language	English (US)
Pages (from-to)	1075-1080
Number of pages	6
Journal	Crystal Growth and Design
Volume	12
Issue number	3
DOIs	https://doi.org/10.1021/cg201520z
State	Published - Mar 7 2012

ASJC Scopus subject areas

Chemistry(all)
Materials Science(all)
Condensed Matter Physics

Access to Document

10.1021/cg201520z

Cite this

@article{1b1818910e45436984c8f376783d8982,

title = "Two large-pore metal-organic frameworks derived from a single polytopic strut",

abstract = "Two noninterpenetrated MOFs with strikingly different structures, NU-108-Cu and NU-108-Zn, were prepared from a single hexa-carboxylated ligand. NU-108-Cu contains paddlewheel-coordinated copper ions as nodes and is based on a 3,24 network associated with an inherently noncatenating rht-topology. Modifications introduced in the hexa-carboxylated struts (uniquely placed phenyl spacers) lead to substantial changes in pore sizes, relative to those found in other MOFs based on 3,24 networks and paddlewheel-coordinated copper ions. NU-108-Zn features a new net based on (3,3,6)-connecter and octadehral Zn 4O nodes in which all struts lie in a-b planes.",

author = "Ibrahim Eryazici and Farha, {Omar K.} and Hauser, {Brad G.} and Yazaydin, {A. {\"O}zg{\"u}r} and Sarjeant, {Amy A.} and Nguyen, {Sonbinh T.} and Hupp, {Joseph T.}",

year = "2012",

month = mar,

day = "7",

doi = "10.1021/cg201520z",

language = "English (US)",

volume = "12",

pages = "1075--1080",

journal = "Crystal Growth and Design",

issn = "1528-7483",

publisher = "American Chemical Society",

number = "3",

}

TY - JOUR

T1 - Two large-pore metal-organic frameworks derived from a single polytopic strut

AU - Eryazici, Ibrahim

AU - Farha, Omar K.

AU - Hauser, Brad G.

AU - Yazaydin, A. Özgür

AU - Sarjeant, Amy A.

AU - Nguyen, Sonbinh T.

AU - Hupp, Joseph T.

PY - 2012/3/7

Y1 - 2012/3/7

N2 - Two noninterpenetrated MOFs with strikingly different structures, NU-108-Cu and NU-108-Zn, were prepared from a single hexa-carboxylated ligand. NU-108-Cu contains paddlewheel-coordinated copper ions as nodes and is based on a 3,24 network associated with an inherently noncatenating rht-topology. Modifications introduced in the hexa-carboxylated struts (uniquely placed phenyl spacers) lead to substantial changes in pore sizes, relative to those found in other MOFs based on 3,24 networks and paddlewheel-coordinated copper ions. NU-108-Zn features a new net based on (3,3,6)-connecter and octadehral Zn 4O nodes in which all struts lie in a-b planes.

AB - Two noninterpenetrated MOFs with strikingly different structures, NU-108-Cu and NU-108-Zn, were prepared from a single hexa-carboxylated ligand. NU-108-Cu contains paddlewheel-coordinated copper ions as nodes and is based on a 3,24 network associated with an inherently noncatenating rht-topology. Modifications introduced in the hexa-carboxylated struts (uniquely placed phenyl spacers) lead to substantial changes in pore sizes, relative to those found in other MOFs based on 3,24 networks and paddlewheel-coordinated copper ions. NU-108-Zn features a new net based on (3,3,6)-connecter and octadehral Zn 4O nodes in which all struts lie in a-b planes.

UR - http://www.scopus.com/inward/record.url?scp=84857982036&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84857982036&partnerID=8YFLogxK

U2 - 10.1021/cg201520z

DO - 10.1021/cg201520z

M3 - Article

AN - SCOPUS:84857982036

SN - 1528-7483

VL - 12

SP - 1075

EP - 1080

JO - Crystal Growth and Design

JF - Crystal Growth and Design

IS - 3

ER -

Two large-pore metal-organic frameworks derived from a single polytopic strut

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

CCDC 878099: Experimental Crystal Structure Determination

CCDC 878100: Experimental Crystal Structure Determination

Cite this

Two large-pore metal-organic frameworks derived from a single polytopic strut

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Datasets

CCDC 878099: Experimental Crystal Structure Determination

CCDC 878100: Experimental Crystal Structure Determination

Cite this