Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

O. V. Magdysyuk; F. Adams; H. P. Liermann; I. Spanopoulos; P. N. Trikalitis; M. Hirscher; R. E. Morris; M. J. Duncan; L. J. McCormick; R. E. Dinnebier

doi:10.1039/c4cp03298e

Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

O. V. Magdysyuk^*, F. Adams, H. P. Liermann, I. Spanopoulos, P. N. Trikalitis, M. Hirscher, R. E. Morris, M. J. Duncan, L. J. McCormick, R. E. Dinnebier

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.

Original language	English (US)
Pages (from-to)	23908-23914
Number of pages	7
Journal	Physical Chemistry Chemical Physics
Volume	16
Issue number	43
DOIs	https://doi.org/10.1039/c4cp03298e
State	Published - Oct 15 2014
Externally published	Yes

ASJC Scopus subject areas

Physics and Astronomy(all)
Physical and Theoretical Chemistry

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title = "Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8",

abstract = "An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.",

author = "Magdysyuk, {O. V.} and F. Adams and Liermann, {H. P.} and I. Spanopoulos and Trikalitis, {P. N.} and M. Hirscher and Morris, {R. E.} and Duncan, {M. J.} and McCormick, {L. J.} and Dinnebier, {R. E.}",

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doi = "10.1039/c4cp03298e",

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T1 - Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

AU - Magdysyuk, O. V.

AU - Adams, F.

AU - Liermann, H. P.

AU - Spanopoulos, I.

AU - Trikalitis, P. N.

AU - Hirscher, M.

AU - Morris, R. E.

AU - Duncan, M. J.

AU - McCormick, L. J.

AU - Dinnebier, R. E.

PY - 2014/10/15

Y1 - 2014/10/15

N2 - An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.

AB - An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.

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U2 - 10.1039/c4cp03298e

DO - 10.1039/c4cp03298e

M3 - Article

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AN - SCOPUS:84908010493

SN - 1463-9076

VL - 16

SP - 23908

EP - 23914

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

IS - 43

ER -

Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

Abstract

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