Understanding the adsorption mechanism of noble gases Kr and Xe in CPO-27-Ni, CPO-27-Mg, and ZIF-8

O. V. Magdysyuk*, F. Adams, H. P. Liermann, I. Spanopoulos, P. N. Trikalitis, M. Hirscher, R. E. Morris, M. J. Duncan, L. J. McCormick, R. E. Dinnebier

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

44 Scopus citations

Abstract

An experimental study of Xe and Kr adsorption in metal-organic frameworks CPO-27-Ni, CPO-27-Mg, and ZIF-8 was carried out. In situ synchrotron X-ray powder diffraction experiments allowed precise determination of the adsorption sites and sequence of their filling with increasing of gas pressure at different temperatures. Structural investigations were used for interpretation of gas adsorption measurements.

Original languageEnglish (US)
Pages (from-to)23908-23914
Number of pages7
JournalPhysical Chemistry Chemical Physics
Volume16
Issue number43
DOIs
StatePublished - Oct 15 2014

ASJC Scopus subject areas

  • General Physics and Astronomy
  • Physical and Theoretical Chemistry

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