Unprecedented sulfone-functionalized metal-organic frameworks and gas-sorption properties

Eleftheria Neofotistou, Christos D Malliakas, Pantelis N. Trikalitis

Research output: Contribution to journalArticlepeer-review

112 Scopus citations

Abstract

A study was conducted to demonstrate significant sulfone-functionalized metal-organic frameworks (MOF) and gas sorption properties. The ligand (1,1'-biphenyl)-4,4'-dicarboxylic acid was functionalized with -SO3H groups and used as a linker to construct coordination polymers and conduct the investigations. The sulfone (-SO2) derivative of (1,1'-biphenyl)-4, 4'-dicarboxylic acid was isolated to conduct the investigations. The investigations revealed two novel three dimensional (3D) non-isoreticular porous MOFs with specific structures. The MOFs were isolated from controlled solvothermal reactions between (1,1'-biphenyl)-4,4'-dicarboxylic acid and Zn(NO3)2·6H2O. The unique structures of the MOFs were demonstrated as UoC-1 and UoC-2 that included the formation of novel inorganic secondary building units (SBUs) with significant double organic bridging connectivity in all directions.

Original languageEnglish (US)
Pages (from-to)4523-4527
Number of pages5
JournalChemistry - A European Journal
Volume15
Issue number18
DOIs
StatePublished - Apr 27 2009

Keywords

  • Adsorption
  • Carbon dioxide
  • Coordination polymers
  • Metal-organic frameworks
  • Sulfone

ASJC Scopus subject areas

  • Catalysis
  • Organic Chemistry

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