Abstract
Many natural and industrial processes involve a complex set of competing reactions that include several different species. Detailed kinetic modeling of such systems can shed light on the important pathways involved in various transformations and therefore can be used to optimize the process conditions for the desired product composition and properties. This review focuses on elucidating the various components involved in modeling the kinetics of pyrolysis and oxidation of polymers. The elementary free radical steps that constitute the chain reaction mechanism of gas-phasenonpolar liquid-phase processes are outlined. Specification of the rate coefficients of the various reaction families, which is central to the theme of kinetics, is described. Construction of the reaction network on the basis of the types of end groups and reactive moieties in a polymer chain is discussed. Modeling frameworks based on the method of moments and kinetic Monte Carlo are evaluated using illustrations. Finally, the prospects and challenges in modeling biomass conversion are addressed.
| Original language | English (US) |
|---|---|
| Pages (from-to) | 29-54 |
| Number of pages | 26 |
| Journal | Annual Review of Chemical and Biomolecular Engineering |
| Volume | 3 |
| DOIs | |
| State | Published - Jul 2012 |
Keywords
- Evans-Polanyi relationship
- Free radicals
- Kinetic Monte Carlo
- Moment-based models
- Oxidation
- Pyrolysis
- Rate coefficients
ASJC Scopus subject areas
- General Chemistry
- General Chemical Engineering