Use of hydrazine in the hydrothermal synthesis of chalcogenides: The neutral framework material [M n2SnS 4H 4) 2]

Manolis J. Manos; Mercouri Kanatzidis

doi:10.1021/ic900517u

Use of hydrazine in the hydrothermal synthesis of chalcogenides: The neutral framework material [M _n2SnS ₄H ₄) ₂]

Manolis J. Manos, Mercouri Kanatzidis

Chemistry

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47 Scopus citations

Abstract

The reaction system MiVSn/S/hydrazine/water at ∼150°C afforded [Mn ₂SnS ₄(N ₂H ₄) ₂] (1). The compound has a unique neutral three-dimensional framework with bridging hydrazine ligands and a variety of interconnectivity modes between MnL ₆ (L = N, S) octahedra. The complex structure of 1 leads to strong antiferromagnetic interactions between the Mn ²⁺ centers and ordering at ∼41 K. The stabilization of 1 underscores the high potential of hydrazine to promote the formation of novel chalcogenide materials under solvothermal conditions.

Original language	English (US)
Pages (from-to)	4658-4660
Number of pages	3
Journal	Inorganic Chemistry
Volume	48
Issue number	11
DOIs	https://doi.org/10.1021/ic900517u
State	Published - Jun 1 2009

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Inorganic Chemistry

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title = "Use of hydrazine in the hydrothermal synthesis of chalcogenides: The neutral framework material [M n2SnS 4H 4) 2]",

abstract = "The reaction system MiVSn/S/hydrazine/water at ∼150°C afforded [Mn 2SnS 4(N 2H 4) 2] (1). The compound has a unique neutral three-dimensional framework with bridging hydrazine ligands and a variety of interconnectivity modes between MnL 6 (L = N, S) octahedra. The complex structure of 1 leads to strong antiferromagnetic interactions between the Mn 2+ centers and ordering at ∼41 K. The stabilization of 1 underscores the high potential of hydrazine to promote the formation of novel chalcogenide materials under solvothermal conditions.",

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Y1 - 2009/6/1

N2 - The reaction system MiVSn/S/hydrazine/water at ∼150°C afforded [Mn 2SnS 4(N 2H 4) 2] (1). The compound has a unique neutral three-dimensional framework with bridging hydrazine ligands and a variety of interconnectivity modes between MnL 6 (L = N, S) octahedra. The complex structure of 1 leads to strong antiferromagnetic interactions between the Mn 2+ centers and ordering at ∼41 K. The stabilization of 1 underscores the high potential of hydrazine to promote the formation of novel chalcogenide materials under solvothermal conditions.

AB - The reaction system MiVSn/S/hydrazine/water at ∼150°C afforded [Mn 2SnS 4(N 2H 4) 2] (1). The compound has a unique neutral three-dimensional framework with bridging hydrazine ligands and a variety of interconnectivity modes between MnL 6 (L = N, S) octahedra. The complex structure of 1 leads to strong antiferromagnetic interactions between the Mn 2+ centers and ordering at ∼41 K. The stabilization of 1 underscores the high potential of hydrazine to promote the formation of novel chalcogenide materials under solvothermal conditions.

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Use of hydrazine in the hydrothermal synthesis of chalcogenides: The neutral framework material [M _n2SnS ₄H ₄) ₂]

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