Variable band filling and an insulator-to-metal transition in a structure-enforced molecular metal

Manuel Almeida; John Gaudiello; Tobin J. Marks; John C. Butler; Henry O. Marcy; Carl R. Kannewurf

doi:10.1016/0379-6779(87)90096-8

Variable band filling and an insulator-to-metal transition in a structure-enforced molecular metal

Manuel Almeida, John Gaudiello, Tobin J. Marks^*, John C. Butler, Henry O. Marcy, Carl R. Kannewurf

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Slurry electrochemical doping of the cofacially-joined phthalocyanine polymer [Si(Pc)O]_n in Et₄N⁺tosylate^- /acetonitrile yields doped polymers of stoichiometry {[Si(Pc)O](tosylate)_y}_n, where y = 0.00 to 0.67. Charge transport data show a continous evolution of properties, from those of an insulator to those (at y {greater-than or approximate} 0.20) of a molecular metal.

Original language	English (US)
Pages (from-to)	261-266
Number of pages	6
Journal	Synthetic Metals
Volume	21
Issue number	1-3
DOIs	https://doi.org/10.1016/0379-6779(87)90096-8
State	Published - Jan 1 1987
Event	Proc of the Conf on Electron Processes in Conduct Polym, Part III - Vadstena, Swed Duration: Aug 18 1986 → Aug 20 1986

ASJC Scopus subject areas

Electronic, Optical and Magnetic Materials
Condensed Matter Physics
Mechanics of Materials
Mechanical Engineering
Metals and Alloys
Materials Chemistry

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10.1016/0379-6779(87)90096-8

Cite this

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title = "Variable band filling and an insulator-to-metal transition in a structure-enforced molecular metal",

abstract = "Slurry electrochemical doping of the cofacially-joined phthalocyanine polymer [Si(Pc)O]n in Et4N+tosylate- /acetonitrile yields doped polymers of stoichiometry {[Si(Pc)O](tosylate)y}n, where y = 0.00 to 0.67. Charge transport data show a continous evolution of properties, from those of an insulator to those (at y {greater-than or approximate} 0.20) of a molecular metal.",

author = "Manuel Almeida and John Gaudiello and Marks, {Tobin J.} and Butler, {John C.} and Marcy, {Henry O.} and Kannewurf, {Carl R.}",

note = "Funding Information: This research was supported by the NSF through the Northwestern Materials Research Center (Grant DMR82-16972, T. J .M. and C. R. K.) and by the Office of Naval Research (T. J. M. and C, R. K.). M. A. thanks NATO for a postdoctoral fellowship.; Proc of the Conf on Electron Processes in Conduct Polym, Part III ; Conference date: 18-08-1986 Through 20-08-1986",

year = "1987",

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doi = "10.1016/0379-6779(87)90096-8",

language = "English (US)",

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pages = "261--266",

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TY - JOUR

T1 - Variable band filling and an insulator-to-metal transition in a structure-enforced molecular metal

AU - Almeida, Manuel

AU - Gaudiello, John

AU - Marks, Tobin J.

AU - Butler, John C.

AU - Marcy, Henry O.

AU - Kannewurf, Carl R.

N1 - Funding Information: This research was supported by the NSF through the Northwestern Materials Research Center (Grant DMR82-16972, T. J .M. and C. R. K.) and by the Office of Naval Research (T. J. M. and C, R. K.). M. A. thanks NATO for a postdoctoral fellowship.

PY - 1987/1/1

Y1 - 1987/1/1

N2 - Slurry electrochemical doping of the cofacially-joined phthalocyanine polymer [Si(Pc)O]n in Et4N+tosylate- /acetonitrile yields doped polymers of stoichiometry {[Si(Pc)O](tosylate)y}n, where y = 0.00 to 0.67. Charge transport data show a continous evolution of properties, from those of an insulator to those (at y {greater-than or approximate} 0.20) of a molecular metal.

AB - Slurry electrochemical doping of the cofacially-joined phthalocyanine polymer [Si(Pc)O]n in Et4N+tosylate- /acetonitrile yields doped polymers of stoichiometry {[Si(Pc)O](tosylate)y}n, where y = 0.00 to 0.67. Charge transport data show a continous evolution of properties, from those of an insulator to those (at y {greater-than or approximate} 0.20) of a molecular metal.

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T2 - Proc of the Conf on Electron Processes in Conduct Polym, Part III

Y2 - 18 August 1986 through 20 August 1986

ER -

Variable band filling and an insulator-to-metal transition in a structure-enforced molecular metal

Abstract

ASJC Scopus subject areas

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