The pathways for energy transfer between CH3Br and HCN have been determined along with their relative importance. The rate of vibrational energy transfer from CH3Br(ν6) to HCN(ν2 has been determined to be 75 ± 25 ms-1 Torr-1. The factors which determine the relative importance of intermolecular vibrational energy transfer pathways will be discussed.
ASJC Scopus subject areas
- Physics and Astronomy(all)
- Physical and Theoretical Chemistry