Vibration-vibration energy transfer processes in liquid xenon: a measurement of the rate constant for Hcl({curly logical or} = 2) + HCl({curly logical or} = 0) → 2HCl({curly logical or} = 1)

Yannis P. Vlahoyannis; Herman Krueger; J. Thomas Knudtson; Eric Weitz

doi:10.1016/0009-2614(85)85524-X

Vibration-vibration energy transfer processes in liquid xenon: a measurement of the rate constant for Hcl({curly logical or} = 2) + HCl({curly logical or} = 0) → 2HCl({curly logical or} = 1)

Yannis P. Vlahoyannis^*, Herman Krueger, J. Thomas Knudtson, Eric Weitz

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The rate constant for the deactivation of HCl(ν = 2) by HCl has been measured in liquid Xe at 208 K. Rate constants for deactivation of HCl(ν = 2) by HClCCl₂ were also measured at 208 K in the gas phase and in liquid Xe solutions. Both processes were found to be accelerated by the solution environment. The possible physical reasons for this enhancement are discussed.

Original language	English (US)
Pages (from-to)	272-278
Number of pages	7
Journal	Chemical Physics Letters
Volume	121
Issue number	3
DOIs	https://doi.org/10.1016/0009-2614(85)85524-X
State	Published - Nov 8 1985

Funding

We would bke to thank the Army Research Office for support of this work under contract DAAG-29-82-K0125 We would also like to acknowledge partial support of this work by the donors of the Petroleum Research Fund admmlstered by the American Chemrcal Society under grant 133366C6 and by the National Science Foundation under grant CHE-85 06957 We thank Professor G. Schatz for very useful conversations.

ASJC Scopus subject areas

General Physics and Astronomy
Physical and Theoretical Chemistry

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@article{0d6ab24b2083474eb3d5033eac56ff50,

title = "Vibration-vibration energy transfer processes in liquid xenon: a measurement of the rate constant for Hcl({curly logical or} = 2) + HCl({curly logical or} = 0) → 2HCl({curly logical or} = 1)",

abstract = "The rate constant for the deactivation of HCl(ν = 2) by HCl has been measured in liquid Xe at 208 K. Rate constants for deactivation of HCl(ν = 2) by HClCCl2 were also measured at 208 K in the gas phase and in liquid Xe solutions. Both processes were found to be accelerated by the solution environment. The possible physical reasons for this enhancement are discussed.",

author = "Vlahoyannis, {Yannis P.} and Herman Krueger and Knudtson, {J. Thomas} and Eric Weitz",

note = "Funding Information: We would bke to thank the Army Research Office for support of this work under contract DAAG-29-82-K0125 We would also like to acknowledge partial support of this work by the donors of the Petroleum Research Fund admmlstered by the American Chemrcal Society under grant 133366C6 and by the National Science Foundation under grant CHE-85 06957 We thank Professor G. Schatz for very useful conversations.",

year = "1985",

month = nov,

day = "8",

doi = "10.1016/0009-2614(85)85524-X",

language = "English (US)",

volume = "121",

pages = "272--278",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier",

number = "3",

}

Vibration-vibration energy transfer processes in liquid xenon: a measurement of the rate constant for Hcl({curly logical or} = 2) + HCl({curly logical or} = 0) → 2HCl({curly logical or} = 1). / Vlahoyannis, Yannis P.; Krueger, Herman; Knudtson, J. Thomas et al.
In: Chemical Physics Letters, Vol. 121, No. 3, 08.11.1985, p. 272-278.

Research output: Contribution to journal › Article › peer-review

TY - JOUR

T1 - Vibration-vibration energy transfer processes in liquid xenon

T2 - a measurement of the rate constant for Hcl({curly logical or} = 2) + HCl({curly logical or} = 0) → 2HCl({curly logical or} = 1)

AU - Vlahoyannis, Yannis P.

AU - Krueger, Herman

AU - Knudtson, J. Thomas

AU - Weitz, Eric

N1 - Funding Information: We would bke to thank the Army Research Office for support of this work under contract DAAG-29-82-K0125 We would also like to acknowledge partial support of this work by the donors of the Petroleum Research Fund admmlstered by the American Chemrcal Society under grant 133366C6 and by the National Science Foundation under grant CHE-85 06957 We thank Professor G. Schatz for very useful conversations.

PY - 1985/11/8

Y1 - 1985/11/8

N2 - The rate constant for the deactivation of HCl(ν = 2) by HCl has been measured in liquid Xe at 208 K. Rate constants for deactivation of HCl(ν = 2) by HClCCl2 were also measured at 208 K in the gas phase and in liquid Xe solutions. Both processes were found to be accelerated by the solution environment. The possible physical reasons for this enhancement are discussed.

AB - The rate constant for the deactivation of HCl(ν = 2) by HCl has been measured in liquid Xe at 208 K. Rate constants for deactivation of HCl(ν = 2) by HClCCl2 were also measured at 208 K in the gas phase and in liquid Xe solutions. Both processes were found to be accelerated by the solution environment. The possible physical reasons for this enhancement are discussed.

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U2 - 10.1016/0009-2614(85)85524-X

DO - 10.1016/0009-2614(85)85524-X

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VL - 121

SP - 272

EP - 278

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 3

ER -

Vibration-vibration energy transfer processes in liquid xenon: a measurement of the rate constant for Hcl({curly logical or} = 2) + HCl({curly logical or} = 0) → 2HCl({curly logical or} = 1)

Abstract

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ASJC Scopus subject areas

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