Vibrational energy transfer pathways in CH3F under weak and strong excitation conditions: A comparison

V. A. Apkarian*, J. M. Lindquist, Eric Weitz

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Energy transfer processes in CH3F have been reinvestigated under high excitation conditions with and without added rare gas via a mathematical model developed as a consequence of studies under low excitation. The model can be used to describe energy transfer under high excitation conditions with the inclusion of an additional state and energy transfer pathways coupling that state to others in the model. A conclusion using this model is that population from 3ν3 does not significantly fill ν14 or 2(ν25) even in the high excitation regime. It is also concluded that multiple photon absorption takes place under high excitation conditions.

Original languageEnglish (US)
Pages (from-to)328-334
Number of pages7
JournalChemical Physics Letters
Volume112
Issue number4
DOIs
StatePublished - Dec 14 1984

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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