Vibrational relaxation of HCl in HCl/liquid xenon mixtures

J. Thomas Knudtson*, Eric Weitz

*Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

24 Scopus citations

Abstract

The vibrational relaxation of HCl in liquid xenon at -68°C has been studied. Vibrationally excited HCl is created following UV photolysis of HCl. The rate of relaxation of HCl as a function of HCl mole fraction in liquid xenon is the same as the corresponding rate for gas phase HCl at -68°C. Similarly the rate of relaxation of HCl in HClXe collisions is in good agreement with the corresponding gas phase rate. These observations imply that the isolated binary collision model is valid for this system.

Original languageEnglish (US)
Pages (from-to)71-78
Number of pages8
JournalChemical Physics Letters
Volume104
Issue number1
DOIs
StatePublished - Jan 27 1984

ASJC Scopus subject areas

  • Physics and Astronomy(all)
  • Physical and Theoretical Chemistry

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