Water stabilization of Zr6-based metal-organic frameworks via solvent-assisted ligand incorporation

Pravas Deria; Yongchul G. Chung; Randall Q. Snurr; Joseph T. Hupp; Omar K. Farha

doi:10.1039/c5sc01784j

Water stabilization of Zr₆-based metal-organic frameworks via solvent-assisted ligand incorporation

Pravas Deria, Yongchul G. Chung, Randall Q. Snurr, Joseph T. Hupp^*, Omar K. Farha

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

88 Scopus citations

Abstract

Water stability in metal-organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs.

Original language	English (US)
Pages (from-to)	5172-5176
Number of pages	5
Journal	Chemical Science
Volume	6
Issue number	9
DOIs	https://doi.org/10.1039/c5sc01784j
State	Published - Jun 19 2015

ASJC Scopus subject areas

Chemistry(all)

Access to Document

10.1039/c5sc01784j

Cite this

@article{5467eb517b4e46cbaece578d4ded0629,

title = "Water stabilization of Zr6-based metal-organic frameworks via solvent-assisted ligand incorporation",

abstract = "Water stability in metal-organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs.",

author = "Pravas Deria and Chung, {Yongchul G.} and Snurr, {Randall Q.} and Hupp, {Joseph T.} and Farha, {Omar K.}",

year = "2015",

month = jun,

day = "19",

doi = "10.1039/c5sc01784j",

language = "English (US)",

volume = "6",

pages = "5172--5176",

journal = "Chemical Science",

issn = "2041-6520",

publisher = "Royal Society of Chemistry",

number = "9",

}

TY - JOUR

T1 - Water stabilization of Zr6-based metal-organic frameworks via solvent-assisted ligand incorporation

AU - Deria, Pravas

AU - Chung, Yongchul G.

AU - Snurr, Randall Q.

AU - Hupp, Joseph T.

AU - Farha, Omar K.

PY - 2015/6/19

Y1 - 2015/6/19

N2 - Water stability in metal-organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs.

AB - Water stability in metal-organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs.

UR - http://www.scopus.com/inward/record.url?scp=84938925407&partnerID=8YFLogxK

UR - http://www.scopus.com/inward/citedby.url?scp=84938925407&partnerID=8YFLogxK

U2 - 10.1039/c5sc01784j

DO - 10.1039/c5sc01784j

M3 - Article

C2 - 30155009

SN - 2041-6520

VL - 6

SP - 5172

EP - 5176

JO - Chemical Science

JF - Chemical Science

IS - 9

ER -

Water stabilization of Zr₆-based metal-organic frameworks via solvent-assisted ligand incorporation

Abstract

ASJC Scopus subject areas

Access to Document

Other files and links

Fingerprint

Cite this