Water stabilization of Zr6-based metal-organic frameworks via solvent-assisted ligand incorporation

Pravas Deria; Yongchul G. Chung; Randall Q. Snurr; Joseph T. Hupp; Omar K. Farha

doi:10.1039/c5sc01784j

Water stabilization of Zr₆-based metal-organic frameworks via solvent-assisted ligand incorporation

Pravas Deria, Yongchul G. Chung, Randall Q. Snurr, Joseph T. Hupp^*, Omar K. Farha

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

115 Scopus citations

Abstract

Water stability in metal-organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs.

Original language	English (US)
Pages (from-to)	5172-5176
Number of pages	5
Journal	Chemical Science
Volume	6
Issue number	9
DOIs	https://doi.org/10.1039/c5sc01784j
State	Published - Jun 19 2015

ASJC Scopus subject areas

General Chemistry

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abstract = "Water stability in metal-organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs.",

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AU - Chung, Yongchul G.

AU - Snurr, Randall Q.

AU - Hupp, Joseph T.

AU - Farha, Omar K.

PY - 2015/6/19

Y1 - 2015/6/19

N2 - Water stability in metal-organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs.

AB - Water stability in metal-organic frameworks (MOFs) is critical for several practical applications. While water instability is mainly thought to stem from linker hydrolysis, MOFs with strong, hydrolysis-resistant metal-linker bonds can be susceptible to damage by capillary forces, which cause cavities and channels to collapse during activation from water. This study utilizes metal node functionalization as a strategy to create vapor-stable and recyclable MOFs.

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Water stabilization of Zr₆-based metal-organic frameworks via solvent-assisted ligand incorporation

Abstract

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