@article{91affa72290749c3a66bbf5596aa89cc,
title = "Water-Stable Zirconium-Based Metal–Organic Framework Material with High-Surface Area and Gas-Storage Capacities",
abstract = "We designed, synthesized, and characterized a new Zr-based metal–organic framework material, NU-1100, with a pore volume of 1.53 ccg−1and Brunauer–Emmett–Teller (BET) surface area of 4020 m2g−1; to our knowledge, currently the highest published for Zr-based MOFs. CH4/CO2/H2adsorption isotherms were obtained over a broad range of pressures and temperatures and are in excellent agreement with the computational predictions. The total hydrogen adsorption at 65 bar and 77 K is 0.092 g g−1, which corresponds to 43 g L−1. The volumetric and gravimetric methane-storage capacities at 65 bar and 298 K are approximately 180 vSTP/v and 0.27 g g−1, respectively.",
keywords = "gas storage, hydrogen, metal–organic frameworks, methane, zirconium",
author = "Gutov, {Oleksii V.} and Wojciech Bury and Gomez-Gualdron, {Diego A.} and Vaiva Krungleviciute and David Fairen-Jimenez and Mondloch, {Joseph E.} and Sarjeant, {Amy A.} and Al-Juaid, {Salih S.} and Snurr, {Randall Q.} and Hupp, {Joseph T.} and Taner Yildirim and Farha, {Omar K.}",
note = "Funding Information: O.K.F., J.T.H., and R.Q.S. thank DOE ARPA-E and the Stanford Global Climate and Energy Project for support of work relevant to methane and CO2, respectively. T.Y. acknowledges support by the U.S. Department of Energy through BES Grant No. DE-FG02-08ER46522. W.B. acknowledges support from the Foundation for Polish Science through the “Kolumb” Program. D.F.J. acknowledges the Royal Society (UK) for a University Research Fellowship. This material is based on work supported by the National Science Foundation (grant CHE-1048773). Publisher Copyright: {\textcopyright} 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim",
year = "2014",
month = sep,
day = "22",
doi = "10.1002/chem.201402895",
language = "English (US)",
volume = "20",
pages = "12389--12393",
journal = "Chemistry - A European Journal",
issn = "0947-6539",
publisher = "Wiley-VCH Verlag",
number = "39",
}