Abstract
A fluorescence technique is used to determine critical micelle concentrations (CMCs) of styrene-containing block and gradient copolymers dispersed within a homopolymer. Block copolymer composition and molecular weight are varied to determine what factors impact the CMC. Gradient copolymers are shown to have higher CMCs than block copolymers due to the gradient in comonomer composition along the copolymer backbone. Gradient copolymers can be more effective as compatibilizing agents, as they are less likely to be trapped within micelles upon melt processing.
| Original language | English (US) |
|---|---|
| Title of host publication | 67th Annual Technical Conference of the Society of Plastics Engineers 2009, ANTEC 2009 |
| Pages | 2651-2656 |
| Number of pages | 6 |
| Volume | 5 |
| State | Published - Nov 25 2009 |
| Event | 67th Annual Technical Conference of the Society of Plastics Engineers 2009, ANTEC 2009 - Chicago, IL, United States Duration: Jun 22 2009 → Jun 24 2009 |
Other
| Other | 67th Annual Technical Conference of the Society of Plastics Engineers 2009, ANTEC 2009 |
|---|---|
| Country | United States |
| City | Chicago, IL |
| Period | 6/22/09 → 6/24/09 |
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Keywords
- Block copolymers
- Compatibilizers
- Fluorescence
- Gradient copolymers
- Micelles
ASJC Scopus subject areas
- Polymers and Plastics
- Chemical Engineering(all)
Cite this
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Why gradient copolymers make better compatibilizers of immiscible polymer blends than block copolymers : Determining critical micelle concentrations of copolymer in homopolymer. / Sandoval, Robert W.; Williams, Daniel E.; Doroudian, Golnar; Wong, Christopher L H; Kim, Jungki; Roth, Connie B.; Torkelson, John M.
67th Annual Technical Conference of the Society of Plastics Engineers 2009, ANTEC 2009. Vol. 5 2009. p. 2651-2656.Research output: Chapter in Book/Report/Conference proceeding › Conference contribution
TY - GEN
T1 - Why gradient copolymers make better compatibilizers of immiscible polymer blends than block copolymers
T2 - Determining critical micelle concentrations of copolymer in homopolymer
AU - Sandoval, Robert W.
AU - Williams, Daniel E.
AU - Doroudian, Golnar
AU - Wong, Christopher L H
AU - Kim, Jungki
AU - Roth, Connie B.
AU - Torkelson, John M
PY - 2009/11/25
Y1 - 2009/11/25
N2 - A fluorescence technique is used to determine critical micelle concentrations (CMCs) of styrene-containing block and gradient copolymers dispersed within a homopolymer. Block copolymer composition and molecular weight are varied to determine what factors impact the CMC. Gradient copolymers are shown to have higher CMCs than block copolymers due to the gradient in comonomer composition along the copolymer backbone. Gradient copolymers can be more effective as compatibilizing agents, as they are less likely to be trapped within micelles upon melt processing.
AB - A fluorescence technique is used to determine critical micelle concentrations (CMCs) of styrene-containing block and gradient copolymers dispersed within a homopolymer. Block copolymer composition and molecular weight are varied to determine what factors impact the CMC. Gradient copolymers are shown to have higher CMCs than block copolymers due to the gradient in comonomer composition along the copolymer backbone. Gradient copolymers can be more effective as compatibilizing agents, as they are less likely to be trapped within micelles upon melt processing.
KW - Block copolymers
KW - Compatibilizers
KW - Fluorescence
KW - Gradient copolymers
KW - Micelles
UR - http://www.scopus.com/inward/record.url?scp=70449944892&partnerID=8YFLogxK
UR - http://www.scopus.com/inward/citedby.url?scp=70449944892&partnerID=8YFLogxK
M3 - Conference contribution
AN - SCOPUS:70449944892
SN - 9781615673278
VL - 5
SP - 2651
EP - 2656
BT - 67th Annual Technical Conference of the Society of Plastics Engineers 2009, ANTEC 2009
ER -