Yb8Ge3Sb5, a Metallic Mixed-Valent Zintl Phase Containing the Polymeric 1∞[Ge 34-] Anions

James R. Salvador; Daniel Bilc; S. D. Mahanti; Tim Hogan; Fu Guo; Mercouri G. Kanatzidis

doi:10.1021/ja0395487

Yb₈Ge₃Sb₅, a Metallic Mixed-Valent Zintl Phase Containing the Polymeric ¹_∞[Ge ₃^4-] Anions

James R. Salvador, Daniel Bilc, S. D. Mahanti, Tim Hogan, Fu Guo, Mercouri G. Kanatzidis^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

16 Scopus citations

Abstract

Yb₈Ge₃Sb₅ is a nonclassical Zintl phase with metallic properties arising from the electropositive "spectator" cations of Yb. This compound contains the new Zintl anion ¹_α(Ge₃)^4- and is stabilized via a combination of Yb²⁺ and Yb³⁺ ions.

Original language	English (US)
Pages (from-to)	4474-4475
Number of pages	2
Journal	Journal of the American Chemical Society
Volume	126
Issue number	14
DOIs	https://doi.org/10.1021/ja0395487
State	Published - Apr 14 2004

ASJC Scopus subject areas

Catalysis
General Chemistry
Biochemistry
Colloid and Surface Chemistry

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abstract = "Yb8Ge3Sb5 is a nonclassical Zintl phase with metallic properties arising from the electropositive {"}spectator{"} cations of Yb. This compound contains the new Zintl anion 1α(Ge3)4- and is stabilized via a combination of Yb2+ and Yb3+ ions.",

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AU - Salvador, James R.

AU - Bilc, Daniel

AU - Mahanti, S. D.

AU - Hogan, Tim

AU - Guo, Fu

AU - Kanatzidis, Mercouri G.

PY - 2004/4/14

Y1 - 2004/4/14

N2 - Yb8Ge3Sb5 is a nonclassical Zintl phase with metallic properties arising from the electropositive "spectator" cations of Yb. This compound contains the new Zintl anion 1α(Ge3)4- and is stabilized via a combination of Yb2+ and Yb3+ ions.

AB - Yb8Ge3Sb5 is a nonclassical Zintl phase with metallic properties arising from the electropositive "spectator" cations of Yb. This compound contains the new Zintl anion 1α(Ge3)4- and is stabilized via a combination of Yb2+ and Yb3+ ions.

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Yb₈Ge₃Sb₅, a Metallic Mixed-Valent Zintl Phase Containing the Polymeric ¹_∞[Ge ₃^4-] Anions

Abstract

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