Zirconium(IV) dilanthanum(III) penta-sulfide

Adam D. Raw; James A. Ibers

doi:10.1107/S1600536811045193

Zirconium(IV) dilanthanum(III) penta-sulfide

Adam D. Raw, James A. Ibers^*

^*Corresponding author for this work

Chemistry

Research output: Contribution to journal › Article › peer-review

Abstract

Zirconium(IV) dilanthanum(III) penta-sulfide, ZrLa₂S ₅, crystallizes with four formula units in the space group Pnma in the U₃S₅ structure type. The asymmetric unit comprises one Zr, one La and four S atoms. The Zr and three S atoms are situated on mirror planes. The structure consists of LaS₈ face-sharing bicapped distorted trigonal prisms and ZrS₇ edge-sharing monocapped octa-hedra.

Original language	English (US)
Pages (from-to)	i70
Journal	Acta Crystallographica Section E: Structure Reports Online
Volume	67
Issue number	12
DOIs	https://doi.org/10.1107/S1600536811045193
State	Published - Dec 2011

Keywords

R factor = 0.017
T = 100 K
data-to-parameter ratio = 20.2
mean σ(Zr-S) = 0.001Å
single-crystal X-ray study
wR factor = 0.056

ASJC Scopus subject areas

Condensed Matter Physics
Chemistry(all)
Materials Science(all)

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title = "Zirconium(IV) dilanthanum(III) penta-sulfide",

abstract = "Zirconium(IV) dilanthanum(III) penta-sulfide, ZrLa2S 5, crystallizes with four formula units in the space group Pnma in the U3S5 structure type. The asymmetric unit comprises one Zr, one La and four S atoms. The Zr and three S atoms are situated on mirror planes. The structure consists of LaS8 face-sharing bicapped distorted trigonal prisms and ZrS7 edge-sharing monocapped octa-hedra.",

keywords = "R factor = 0.017, T = 100 K, data-to-parameter ratio = 20.2, mean σ(Zr-S) = 0.001{\AA}, single-crystal X-ray study, wR factor = 0.056",

author = "Raw, {Adam D.} and Ibers, {James A.}",

year = "2011",

month = dec,

doi = "10.1107/S1600536811045193",

language = "English (US)",

volume = "67",

pages = "i70",

journal = "Acta Crystallographica Section E: Structure Reports Online",

issn = "1600-5368",

publisher = "International Union of Crystallography",

number = "12",

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TY - JOUR

T1 - Zirconium(IV) dilanthanum(III) penta-sulfide

AU - Raw, Adam D.

AU - Ibers, James A.

PY - 2011/12

Y1 - 2011/12

N2 - Zirconium(IV) dilanthanum(III) penta-sulfide, ZrLa2S 5, crystallizes with four formula units in the space group Pnma in the U3S5 structure type. The asymmetric unit comprises one Zr, one La and four S atoms. The Zr and three S atoms are situated on mirror planes. The structure consists of LaS8 face-sharing bicapped distorted trigonal prisms and ZrS7 edge-sharing monocapped octa-hedra.

AB - Zirconium(IV) dilanthanum(III) penta-sulfide, ZrLa2S 5, crystallizes with four formula units in the space group Pnma in the U3S5 structure type. The asymmetric unit comprises one Zr, one La and four S atoms. The Zr and three S atoms are situated on mirror planes. The structure consists of LaS8 face-sharing bicapped distorted trigonal prisms and ZrS7 edge-sharing monocapped octa-hedra.

KW - R factor = 0.017

KW - T = 100 K

KW - data-to-parameter ratio = 20.2

KW - mean σ(Zr-S) = 0.001Å

KW - single-crystal X-ray study

KW - wR factor = 0.056

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U2 - 10.1107/S1600536811045193

DO - 10.1107/S1600536811045193

M3 - Article

C2 - 22199468

AN - SCOPUS:83155191767

SN - 1600-5368

VL - 67

SP - i70

JO - Acta Crystallographica Section E: Structure Reports Online

JF - Acta Crystallographica Section E: Structure Reports Online

IS - 12

ER -

Zirconium(IV) dilanthanum(III) penta-sulfide

Abstract

Keywords

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